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鋰離子電池用鹵化物固態電解質:專利情形分析(2024年)Halide Solid Electrolytes for Li-ion Batteries Patent Landscape Analysis 2024 |
本報告分析了與鋰離子電池用鹵化物固體電解質相關的專利申請和出版物的趨勢,並研究了專利出版物數量(依國家和專利持有人)、依細分市場劃分的主要專利持有人和新進者的趨勢。專利等)等我們將向您發送一份 Excel 文件,其中總結了要分析的專利(總共超過 330 項)。
近幾十年來,固態鋰離子電池由於其安全性和高能量密度潛力的顯著優勢而引起了廣泛的關注。具有快速離子傳輸和優異穩定性的固態電解質(SE)對於這種有前途的下一代鋰電池的商業化至關重要。因此,對無機固體電解質如硫化物電解質和氧化物電解質的研究已經積極進行。然而,兩者都未能實現電導率和穩定性之間的最佳平衡。氧化物的晶界阻抗高,硫化物的穩定性低。然而,鹵化物基固體電解質具有室溫離子電導率(>10-3 S.cm-1)、與氧化物正極材料良好的相容性以及優異的化學穩定性和可擴展性,因此被認為是其中之一。
對鹵化物固體電解質日益增長的興趣也透過監測固態鋰離子電池相關專利得到證實。截至2023年9月,已公開與鋰離子電池鹵化物固態電解質材料相關的專利330餘項。對於從事固態電池行業的公司來說,現在至關重要的是從技術、競爭和智慧財產權 (IP) 的角度審查這些新興材料。
本報告分析了主要專利持有者(專利受讓人)公司的專利組合實力、主要技術和應用領域。它還概述了專利技術及其使用的現狀和趨勢。此外,我們還研究了該領域領先企業和新進入者的策略和技術方向。
專利涵蓋了要求保護的材料成分(LiMX4、Li3MX6、單獨的鹵化物材料、帶殼的鹵化物材料、與其他材料混合的鹵化物材料)、要求保護的製造方法(機械化學、共熔、液相)以及課題/解決方案,以及本發明公開了室溫下最好的材料/離子電導率。
Panasonic/Sanyo在鹵化物固體電解質專利方面處於領先地位,競爭對手包括Samsung、GLABAT、SVOLT、Saint-Gobain、TDK。此外,我們的智慧財產權分析使我們能夠識別出60 多家在2022 年後首次提交鹵化物相關專利的智慧財產權進入者:EVE Energy、Korea Electronics Technology Institute (KETI)、Liongo New Energy、Qingtao Energy Development、Global Graphene等。80%的新專利申請者來自中國。專門的部分重點在於主要公司(Panasonic、Samsung、Saint-Govain、GLABAT、SVOLT、EVE Energy、University of Western Ontario、TDK、Toyota等)持有的智慧財產權組合。對於每一項,我們都提供了與鹵化物固體電解質相關的專利組合概述以及關鍵專利技術的描述。
該報告還包括一個內容廣泛的 Excel 資料庫,其中包含分析的所有專利。這個方便的專利資料庫可進行多標準搜索,包括專利公開號、更新線上資料庫的超連結(文字、法律狀態等)、優先權日期、標題、摘要、專利受讓人、部分(問題/解決方案、材料成分、鹵化物)劑型、合成方法等)。
Baoneng Group、Baowu Steel Group、BASF、Beijing Institute of Technology、BYD、China Automotive Battery Research Institute、China Electrics、Corning、EVE Energy、FAW (China First Automobile Works)、Global Graphene、GRINM (General Research Institute for Nonferrous Metals)/GRIMAT、GRIREM Advanced Materials、GTC Power、Guolian Automobile Power Battery Research Institute (GLABAT)、Guoxuan High Tech Power Energy/Gotion、Hanyang University、Hyundai/Kia、Institute of Chemistry - Chinese Academy of Sciences、Korea Electronics Technology Institute (KETI)、Liongo New Energy Technology、Nankai University、Nanmu Nanotechnology、Nichia、Panasonic/Sanyo、QingTao Energy Development、Rare Earth Functional Materials Innovation Center、Saint-Gobain、Samsung、Shenzhen University、Silver Leaf Element、Solvay、South University of Science & Technology of China (SUSTech)、SVOLT/Fengchao Energy Technology、TDK、Toyota、Tsinghua Shenzhen International Graduate School、University of Maryland、University of Waterloo、University of Western Ontario、University of Science and Technology of China (USTC)、Xi'an Jiaotong University、Yonsei University、Zengzhou New Century Materials Genome Institute、Zhejiang University等。
Solid-state Li-ion batteries have garnered significant attention in recent decades due to their notable advantages of safety and potential for high energy density. Solid electrolytes (SE) with rapid ionic transport and excellent stability are essential for the commercialization of this promising next-generation of Lithium batteries. Hence, there has been extensive exploration of inorganic solid electrolytes, including sulfide- and oxide-based electrolytes. Unfortunately, both have been unable to strike an optimal balance between conductivity and stability. Oxides suffer from high impedance of grain boundaries, while sulfides experience poor stability. However, halide-based solid electrolytes are increasingly being recognized as one of the most promising options for solid-state Li-ion batteries, owing to their decent room temperature ionic conductivity (>10-3 S.cm-1), good compatibility with oxide cathode materials, excellent chemical stability, and scalability.
The increasing interest in halide solid electrolytes has been observed while monitoring patents on solid-state Li-ion batteries. As of September 2023, over 330 patent families have been published on halide solid electrolyte materials for Li-ion batteries. It is now crucial for companies operating in the solid-state battery industry to closely examine these emerging materials from technological, competitive, and intellectual property (IP) perspectives.
In this context, Knowmade is releasing a new patent landscape report that focuses on halide solid electrolyte materials for Li-ion batteries. In this report, Knowmade's analysts have selected and analyzed over 860 patents and patent applications from more than 330 patent families (inventions) filed by 110+ different entities. The report provides a detailed analysis of the IP landscape and noteworthy patents concerning halide solid electrolyte materials. This new IP report is complementary to our previous patent landscape reports and patent monitors on solid-state batteries.
IP competition analysis should reflect the vision of players with a strategy to enter and develop their business in the solid-state Li-ion battery market. In this report, Knowmade's analysts provide a comprehensive overview of the competitive IP landscape and latest technological developments in this field. The report covers IP dynamics and key trends in terms of patents applications, patent assignees, filing countries, and patented technologies. It also identifies the IP leaders, most active patent applicants, and new entrants in the IP landscape. The report also sheds light on under-the-radar companies and new players in this field.
In this report, we analyze the strength of patent portfolios and the technology and application focus of key patent assignees. An overview of the current status and trends of patented technologies and their applications is also provided. Furthermore, the report examines the strategic and technological directions of both leading companies and newcomers in the field.
The patents have been manually categorized according the claimed material compositions (LiMX4, Li3MX6, halide material alone, halide material with a shell, halide material mixed with another material), the claimed manufacturing methods (mechano-chemical, co-melting, liquid-phase), as well as the challenges/solutions and the best materials/ionic conductivities at room temperature disclosed by the inventions.
Panasonic/Sanyo is leading the halide solid electrolytes patent landscape, challenged by Samsung, GLABAT, SVOLT, Saint-Gobain, and TDK. Additionally, the IP analysis allowed us to pinpoint over 60 IP newcomers who filed their first halide-related patents in 2022 or after: EVE Energy, Korea Electronics Technology Institute (KETI), Liongo New Energy, Qingtao Energy Development, Global Graphene, etc. 80% of new entrants in the patent landscape come from China. In a dedicated section, we focus on the IP portfolios held by key players (Panasonic, Samsung, Saint-Gobain, GLABAT, SVOLT, EVE Energy, University of Western Ontario, TDK, Toyota, etc.). For each, we provide an overview of their patent portfolio related to halide solid electrolytes and a description of their key patented technologies.
This report also includes an extensive Excel database with all patents analyzed in this study. This useful patent database allows for multi-criteria searches and includes patent publication numbers, hyperlinks to an updated online database (original documents, legal status, etc.), priority date, title, abstract, patent assignees, and segments (challenges/solutions, material composition, halide formula, synthesis methods, etc.).
Baoneng Group, Baowu Steel Group, BASF, Beijing Institute of Technology, BYD, China Automotive Battery Research Institute, China Electrics, Corning, EVE Energy, FAW (China First Automobile Works), Global Graphene, GRINM (General Research Institute for Nonferrous Metals) / GRIMAT, GRIREM Advanced Materials, GTC Power, Guolian Automobile Power Battery Research Institute (GLABAT), Guoxuan High Tech Power Energy / Gotion, Hanyang University, Hyundai / Kia, Institute of Chemistry - Chinese Academy of Sciences, Korea Electronics Technology Institute (KETI), Liongo New Energy Technology, Nankai University, Nanmu Nanotechnology, Nichia, Panasonic / Sanyo, QingTao Energy Development, Rare Earth Functional Materials Innovation Center, Saint-Gobain, Samsung, Shenzhen University, Silver Leaf Element, Solvay, South University of Science & Technology of China (SUSTech), SVOLT / Fengchao Energy Technology, TDK, Toyota, Tsinghua Shenzhen International Graduate School, University of Maryland, University of Waterloo, University of Western Ontario, University of Science and Technology of China (USTC), Xi'an Jiaotong University, Yonsei University, Zengzhou New Century Materials Genome Institute, Zhejiang University, and more.